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Amino acids (AAs) are a key target in the search for life beyond Earth due to their extensive role in the machinery of all known life, persistence over geologic timescales, and analytical detectability. However, AAs can also arise from abiotic processes on planets and in space. For example, material from asteroid Bennu contained 33 AAs, including 15 of the 20 proteinogenic AAs that are fundamental to life's functions. Distinguishing life from non-life based on AAs in a sample remains an unsolved problem, particularly when their isotopic and structural signatures (e.g., chirality) could be altered via physicochemical processes. Here we introduce LUMOS (Life Unveiled via Molecular Orbital Signatures), a statistical framework that distinguishes life from non-life by analyzing the distribution of abundance-weighted HOMO-LUMO gap (HLG) values of AAs within a sample. Compilation of AAs datasets from diverse environments and provenances revealed that abiotic samples display highly uniform distributions of AAs HLGs. In contrast, biotic samples show greater variance and preference towards AAs with lower HLG, likely reflecting the need for life to control when, where, and how chemical reactions occur. LUMOS achieves >95% accuracy in distinguishing biotic versus abiotic provenance across diverse environmental and extraterrestrial conditions. These results suggest that varied molecular reactivity within biochemical systems may be a universal feature of life, representing an agnostic biosignature unlinked to the specific set of AAs used by life as we know it. LUMOS is compatible with existing analytical instrumentation, applicable to returned samples or in situ analyses. Broader characterization of abiotic and biotic environments will further refine the chemical boundaries separating biotic from abiotic chemical systems.
We present the first results from the POSEIDON survey, aimed at constraining the dynamical origins of transiting Neptunes through stellar obliquity measurements. We report Rossiter-McLaughlin observations of two Neptunes, TOI-181 b and TOI-883 b, obtained with high-resolution spectroscopy from Magellan/PFS and WIYN/NEID. TOI-181 b is on a 4.5-day orbit with a sky-projected spin-orbit misalignment $\lambda = 32.0_{-6.5}^{+6.3}\,^{\circ}$ and a low eccentricity ($e<0.12$ with $2\sigma$ confidence). TOI-883 b has a longer orbital period of 10 days with $\lambda = 22_{-14}^{+15}\,^{\circ}$ and eccentricity $e = 0.16 \pm 0.03$. The significant misalignment of TOI-181 b and the significant eccentricity of TOI-883 b are suggestive of high-eccentricity migration for both systems. After adding these and other new measurements to the sample, we analyze the obliquity distribution of the host stars of transiting Neptunes. Earlier studies had suggested that the obliquity distribution is bimodal, with peaks corresponding to aligned orbits and polar orbits; the addition of more measurements has weakened the evidence for bimodality. The current sample appears to be consistent with a population of well-aligned systems and a smaller population with nearly random obliquities. This distribution resembles that observed for more massive planets, suggesting that transiting Jupiters and Neptunes originate from similar dynamical processes.
We present a detailed study of near-infrared (2-4$\rm \mu$m) JWST/NIRSpec spectra of 48 high-redshift ($z=2.53^{+1.32}_{-0.70}$) galaxies detected with ALMA at $>3\sigma$. From a multi-wavelength SED analysis we establish the sample has a a median stellar mass of $\rm\log_{10}(M_\ast/M_\odot)=10.8\pm0.1$ and dust mass of $\rm\log_{10}(M_{\rm d}/M_\odot)=8.7\pm0.1$, covering a broad range of far-infrared luminosity $\rm (\log_{10}(L_{FIR}/L_\odot)=10.9-12.7)$. The majority of sources show no signs of AGN activity, with 40% having either X-ray counterparts $(\rm L_{Xc}>10^{42}erg/s)$, elevated optical line ratios, or broad (FWHM>800 km/s) H$\alpha$ profiles, although we note this is a lower limit due to the stochastic placement of NIRSpec slits. We establish the sample has a median gas-phase metallicity of $12+\log({\rm O/H})=8.71\pm0.02$, as derived from the [NII]/H$\alpha$ ratio, with the most FIR-luminous galaxies ($\rm\log_{10}(L_{\rm FIR}/L_\odot)>12$) falling $0.15\pm0.03$dex above the fundamental metallicity relation. From the [SII] emission-line doublet ratio, we measure a median electron density of $\log_{10}(n_{\rm e}/{\rm cm}^{-3})=2.53\pm0.07$ consistent with less-massive, star-forming, galaxies at the same epoch. For nine galaxies with [OII] and H$\beta$ detections (median $\rm\log_{10}(L_{\rm FIR}/L_\odot)=11.81\pm0.15$), we derive a median observed (dust-uncorrected) ionisation parameter of $\rm\log_{10}(U)=-2.84\pm0.06$. Our results indicate that luminous far-infrared galaxies are massive, chemically evolved systems that appear to deviate from the standard dust and metal production equilibrium observed in less obscured galaxies. This study demonstrates the synergy of JWST and ALMA in unveiling the nature of DSFGs, and highlights the need for a NIRSpec survey of uniformly selected, massive, dust-obscured, galaxies to fully characterise their interstellar medium.
The radiolysis effect of cosmic rays (CRs) plays an important role in the chemistry in molecular clouds. CRs can dissociate the molecules on dust grains, producing reactive suprathermal species and radicals which facilitate the formation of large molecules. We add the radiolysis process and some relevant reactions into the Nautilus astrochemical code. By adjusting some parameters, we investigate the sensitivity of the simulation results of the H2O ice on the removal of reaction-diffusion competition, the removal of non-diffusive chemistry, and the desorption energies of the suprathermal species. We find the model, with a few adjustments of the chemistry, can reproduce the steady-state [H2O2]/[H2O] and [O3]/[O2]_0 abundance ratios in the H2O and O2 radiolysis experiments at any CR flux in the experiments. These adjustments in the model do not fully reproduce the fluence required to reach the steady state. It tends also to overestimate the destruction of H2O as measured in H2O radiolysis experiments. We show that reducing the G-values of H2O radiolysis, which implies an increase in the efficiency of immediate reformation of water locally after ion impact, leads to simulated H2O destruction rates closer to the experiments. The effect of reaction-diffusion competition on the simulation results of H2O ice is significant at $\zeta \lesssim 10^{-14}\ \rm s^{-1}$. The non-diffusive chemistry affects the simulation results at 16 K but not 77K, while the results are sensitive to the desorption energies of suprathermal H, O, O3 and OH at 77 K. Our results show that the steady-state [H2O2]/[H2O] and [O3]/[O2]_0 in experiments can be reproduced by fine-tuning the chemical model, but still call for more constraints on the intermediate pathways in the radiolysis processes, especially the ion chemistry in the ice bulk, as well as activation barriers and branching ratios of the reactions in the network.
Galaxy major mergers are a potential mechanism for triggering active galactic nuclei (AGN) activity, but their role remains debated, particularly beyond the local Universe. We aim to shed light on the merger-AGN connection at $z=0.5$-$2$, exploiting the multi-wavelength datasets and {\it James Webb Space Telescope} (JWST) observations in the COSMOS field. We construct a stellar mass-limited sample and identify AGN via mid-infrared (MIR) colours, X-ray detections, and spectral energy distribution (SED) fitting. We train convolutional neural networks to identify mergers with mock JWST observations. We create non-AGN and non-merger control samples matching the redshift, stellar mass, and star-formation rate distributions of the AGN and mergers. We find AGN to be moderately more frequent in mergers than in non-mergers, with excess ratios ranging from $\sim2.5$ (X-ray AGN) to $\sim1.3$ (MIR) and $\sim 1.1$-1.2 (SED AGN). Similarly, AGN galaxies show a higher merger fraction ($f_{merg}$) than non-AGN controls. We then study $f_{merg}$ as a function of relative and absolute AGN power, utilising the AGN fraction ($f_{AGN}$) and accretion disc luminosity (L$_{disc}$) parameters. We uncover a $f_{merg}$-$f_{AGN}$ relation with two regimes: $f_{merg}$ stays roughly flat for less-dominant AGN ($f_{AGN}<0.8$) but increases at $f_{AGN}>0.8$ for the MIR and X-ray AGN, and more gently for SED AGN, where mergers appear to be the main triggering mechanism. Additionally, $f_{merg}$ increases monotonically as a function of L$_{disc}$, for all AGN types, reaching $f_{merg}>50\%$ for the most luminous AGN (L$_{disc} \gtrsim 10^{46}\,{erg\,s^{-1}}$). Overall, our results suggest that major mergers can trigger AGN out to the cosmic noon at $z\sim2$. Furthermore, the role of major mergers shows a clear dependence on AGN luminosity and remains the principal mechanism for fuelling the most powerful AGN.
We characterize the radius-dependent eccentricity distribution of 347 warm (P = 8-200 days) systems with only one transiting planetary candidate identified during Sectors 1-69 of the TESS mission. Using the ``photoeccentric effect'' in a hierarchical Bayesian framework, we first model the population using discrete planetary size bins (sub-Neptunes, sub-Saturns, and Jovians). We then develop a continuous mixture model with weights governed by a logistic sigmoid function of radius. We find that the warm-single population is best described by two components: a dominant low-eccentricity mode ( <e_low> = 0.070-0.068+0.026) and a secondary dynamically excited mode (<e_high> = 0.616-0.075+0.091). The fraction of planets belonging to this high-eccentricity component increases strongly with planet radius, characterized by a transition at a break radius of R_br = 9.8-1.1+1.4 R_e. This trend places warm sub-Saturns predominantly on the same low-eccentricity track as sub-Neptunes. In contrast, warm Jovians (8--16 R_e) are frequently eccentric, with 59+-13% of the population in the high eccentricity mode. We detect this bimodality at >4sigma, providing statistically significant evidence that warm gas giants are sculpted by two distinct pathways, or a single mechanism with subsequent eccentricity excitation. Finally, we identify a non-negligible tail of highly eccentric sub-Neptunes (1--4 R_e), which comprise 14.9-6.5+5.1% of the population, consistent with excitation by non-transiting external companions.
this https URL . A Python script for an in-depth comparison between BayeSED3 and BAGPIPES is available at this https URL